So a few things...
There is about exactly 2 gallons reserve on my car and at 1 gal you are pushing( Don't ask, I did it for science, lol)
Don't worry about the saddle tanks, on a refueling event LTFT correction stops and the ecm only uses STFT correction for about 7 miles then it locks in the LTFT. Your fuel will be well blended by then. Once you get good at it your LTFT won't have changed after it relocks in. Just don't beat on the car till you see STFT back around one. I always put E in first then top off with 93 just in case some fiat causes my foot to get heavy on the way to Shell.
On the initial tank I'd calculate the entire 19. Now I only calculate what is going in with the 4 segments of the gauge worth 4.25 gallons each. (17 total) This has been a much better system for me and as long as I use my normal brands, trims really don't change. Side note, BP seems to be a bit heavy on the E in my area.
Make sure you use the best top tier you can find as your base fuel
Do you have a blend calculator?
You might also want to look up your seasonal alcohol content based on region at the EPA website.
If you're worried about phase separation (I'm not, I fill up about every 4 days) run a bottle or two of HEET through the system every so often.
Personally I wouldn't get too uptight about your blends. I've tested every possible blend, including straight E85...tuned for it, not tuned for it, basically every inadvisable thing you can think of totaling about 50K between 2 SHO's...Keep in mind, the car will feel at its best when its done right and your stoich is dialed in and your trims are around one.